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Extra info for Fiesers' Reagents for Organic Synthesis (Volume 19)

Example text

JACS118,5818(1996). ,Buchwald, (1996). JoC 61,2'713 Bis(trimethylsilyl) chromate-silica gel. r supportedon silica gel. It has similar oxidizing power toward alcohols as do other chromates (22 examples,7 | -99Vo). SC26,543(1996)' chromate. l (8 80-92Vo). The reaction is sluggish when products examples, reagent affords carbonyl is used. , Shiriny,F. SC26, 649(1996). Bis(triphenylphosphonio)oxide bistriflate. t amine, epoxides undergo a double-elimination reaction, giving conjugated dienes in good yields.

Takeno. M.. l . 3 group is placed saturatedor hydrosilylated with hydrogen or PhSiI:|3,respectively' The silyl at the terminal position of the double bond. Bisttitanocene chloride). t Substituted gllcosl ;roup at the adjacentcarbon on brief rllvcals are obtainedin good yields. , Marks,T. JACS118,9295(1996). rl-i. Y.. T. "/ACSr18,707(1996). 3Molander. JOMC 5U,275 (1996). le95). imidr. ", lhc reagentNsN:Se:NNs (prepared Lt -. 11rr)om temperaturegives the allylic J:-. 2-diamino-3-alkenes' . l Sl 5 J ( 1 9 9 6 ) .

R supportedon silica gel. It has similar oxidizing power toward alcohols as do other chromates (22 examples,7 | -99Vo). SC26,543(1996)' chromate. l (8 80-92Vo). The reaction is sluggish when products examples, reagent affords carbonyl is used. , Shiriny,F. SC26, 649(1996). Bis(triphenylphosphonio)oxide bistriflate. t amine, epoxides undergo a double-elimination reaction, giving conjugated dienes in good yields. Crowded epoxides remain unchanged; thus, the mixture of cis- and trans-cyclododeceneoxides affords a clean mixture of (lE, 3Z)-cyclododecadiene and trans-cy clododeceneoxide (50Voyield).

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