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By Ryoji Noyori

Bargains with simple ideas of uneven catalysis targeting its artificial importance. Covers homogeneous uneven hydrogenation, uneven catalysis through chiral steel complexes, heterogeneous catalysis and non-organometallic catalysis. the gathering of a variety of stereoselective reactions illustrate a variety of suggestions and methodologies in addition to their basic software.

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N. E BUU-Hot,M. D U F O u q F! JACQUIGNON, J. chem. (C)1969 1337. N. €! Buu-Hot, M. MANGANE, E JACQUIGNON, J. Heterocyclic Chem. 7 (1970) 155 Acridon-Synthese JOURDAN-ULLMANN-GOLDBERG durch Cyclisierung von Diphenylamino-o-carbonsauren I mittels Schwefelsaure oder fur viele substituierte Diarylaminocarbonsauren mit Polyphosphorsaure. )hergestellt, die in Gegenwart von Alkalicarbonat und Kupfer erhitzt werden: 18 1. 2. HI Phenylanthranilsaure-Synthese(ULLMANN) H Da die Reaktion wahrscheinlich uber einen nucleophilen Angriff des Arylamin-Stickstoffs auf das halogenierte o-Kohlenstoffatom verlauft, sind sowohl der elektrophile Charakter der o-Chlorbenzoesaure als auch die nucleophile Starke des Amins von Bedeutung fur die Kondensation.

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